Photoshop will not run directly under Linux. You need to use Wine or corssover to run photoshop under Linux. Rest of the stuff should work without any problem. For new user Debian OR CentOS recommend for server OS. Another option is before making switch install Linux inside VMWare or Virtualbox and practice a bit. Once comerftable make a switch.
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Vivek Gite
Linux Evangelist
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 Do you run a Linux? Let's face it, you need help
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